This chapter states the requirements for balances used for materials that must be accurately weighed (see General Notices and Requirements, 8.20). Unless otherwise specified, when substances must be “accurately weighed,” the weighing shall be performed using a balance that is calibrated over the operating range and meets the requirements defined for repeatability and accuracy. For balances used for other applications, the balance repeatability and accuracy should be commensurate with the requirements for its use.

For a discussion of the theoretical basis of these requirements, see Weighing on an Analytical Balance 1251, which may be a helpful—but not mandatory—resource.

Repeatability is assessed by weighing one test weight NLT 10 times. [Note—The test weight must be within the balance's operating range, but the weight need not be calibrated. Because the standard deviation(IRA 1-Jul-2014) is virtually independent of sample mass within the balance's capacity, use of a small test weight, which may be difficult to handle, is not required. ]

Repeatability is satisfactory if two times the standard deviation of the weighed value, divided by the desired smallest net weight (i.e., smallest net weight that the users plan to use on that balance),(IRA 1-Jul-2014) does not exceed 0.10%. If the standard deviation obtained is less than 0.41d, where d is the scale interval, replace this standard deviation with 0.41d. In this case, repeatability is satisfactory if 2 × 0.41d, divided by the desired smallest net weight,(IRA 1-Jul-2014) does not exceed 0.10%.

The accuracy of a balance is satisfactory if its weighing value, when tested with a suitable weight(s), is within 0.10% of the test weight value.

A test weight is suitable if it has a mass between 5% and 100% of the balance's capacity. The test weight's maximum permissible error (mpe), or alternatively its calibration uncertainty, shall be NMT one-third of the applied test limit of the accuracy test. [Note—Applicable standards are the following: ASTM E617 (available from http://www.astm.org) and OIML R 111 (available from http://www.oiml.org). ]