Title: Oxypinocamphone
CAS Registry Number: 10136-65-9
CAS Name: 2-Hydroxy-2,6,6-trimethylbicyclo[3.1.1]heptan-3-one
Additional Names: 2-hydroxy-3-pinanone; 2-hydroxypinocamphone
Trademarks: Camphostene; Oxypinone
Molecular Formula: C10H16O2
Molecular Weight: 168.23
Percent Composition: C 71.39%, H 9.59%, O 19.02%
Literature References: Prepn of l-form: Kuwata, J. Am. Chem. Soc. 59, 2509 (1937); Harispe et al., Bull. Soc. Chim. Fr. 1964, 1035; of dl-form: Kuwata, loc. cit. Stereochemistry: Carlson et al., Tetrahedron Lett. 1968, 5941.
Derivative Type: dl-Form
Properties: Crystals, mp 38.5-39.0°.
Melting point: mp 38.5-39.0°
Derivative Type: l-Form
Properties: Crystals from ether + petr ether, mp 35.5-36.5°. [a]D25 -18.56° (c = 14.44 in alcohol).
Melting point: mp 35.5-36.5°
Optical Rotation: [a]D25 -18.56° (c = 14.44 in alcohol)
Therap-Cat: Respiratory insufficiency.
Status: This monograph has been retired and is no longer subject to revision or update. |