Title: Quinuclidine
CAS Registry Number: 100-76-5
CAS Name: 1-Azabicyclo[2.2.2]octane
Additional Names: 1,4-ethylenepiperidine
Molecular Formula: C7H13N
Molecular Weight: 111.18
Percent Composition: C 75.62%, H 11.79%, N 12.60%
Literature References: Prepn: Löffler, Stietzel, Ber. 42, 124 (1909); Meisenheimer et al., Ann. 420, 191 (1920); Clemo, Metcalfe, J. Chem. Soc. 1937, 1989; Prelog, US 2192840 (1940); Wawzonek et al., J. Am. Chem. Soc. 73, 2806 (1951); Leonard, Elkin, J. Org. Chem. 27, 4635 (1962).
Properties: Prisms from petr ether. Sublimes. mp 156° (sealed tube). Very sol in water and the usual organic solvents.
Melting point: mp 156° (sealed tube)
Derivative Type: Hydrochloride
Molecular Formula: C7H13N.HCl
Molecular Weight: 147.65
Percent Composition: C 56.94%, H 9.56%, N 9.49%, Cl 24.01%
Properties: Crystals from abs ethanol, mp 364-365°.
Melting point: mp 364-365°
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