【药物名称】RGH-5981
化学结构式(Chemical Structure):
参考文献No.40
标题:Thiazolidine derivs., process for the preparation and pharmaceutical compsns. thereof
作者:Dom醤y, G.; Ezer, E.; Harsanyi, K.; Heged黶, B.; Matuz, J.; Pallagi, K.; Szabadkai, I.; Szporny, L.; T閠閚yi, P. (Gedeon Richter Ltd.)
来源:BE 0899132; CH 660592; DE 3409801; ES 8604179; FR 2542740; GB 2140412; US 4616025
合成路线图解说明:

N-Benzyl 2-aminoethanethiol (I) is reacted with 1,1-bis(methylsulfanyl)-2-nitroethene (II) in boiling ethanol to give RGH-5981.

参考文献No.54319
标题:MPTP
作者:Casta馿r, J.; Prous, J.
来源:Drugs Fut 1986,11(5),384
合成路线图解说明:

N-Benzyl 2-aminoethanethiol (I) is reacted with 1,1-bis(methylsulfanyl)-2-nitroethene (II) in boiling ethanol to give RGH-5981.

合成路线图解说明:

The reaction of N-methyl-4-piperidone (II) with phenyllithium (I) in benzene-ethyl ether below 10 C gives 4-hydroxy-1-methyl-4.phenypiperidine (III), which is dehydrated by treating with refuxing concentrated HCl.

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