【药物名称】Cloturin, VUFB-15686
化学结构式(Chemical Structure):
参考文献No.4756
标题:6-Purinyl N-(2-chloroethyl)carbamate and thiocarbamate, a process for their preparation and use thereof. CS 249576
作者:Cerny, A.; Krepelka, J.I.; Melka, M.; Molko, M.; Pokorn? S.; Reichov? R.; Kejhov? I.; Beitov? M.; Grimov? J. (SPOFA - United Pharmaceutical Works)
来源:EP 0186454; JP 1986186382; US 4720497
合成路线图解说明:

The compound can be prepared by reacting mercaptopurine (I) with 2-chloroethylisocyanate (II) in an inert medium at a temperature from 0-50 C, preferably in the presence of an alkaline agent. Suitable inert media for the reaction are dimethylformamide, dimethylsulfoxide, phosphoric acid, hexamethyltriamide or tetramethylurea. Alkaline agents, preferably tertiary organic amines, accelerate the reaction and make the yield of the desired product higher.

参考文献No.120814
标题:CLOTURIN
作者:Melka, M.; Krepelka, J.; Miko, M.
来源:Drugs Fut 1990,15(4),337
合成路线图解说明:

The compound can be prepared by reacting mercaptopurine (I) with 2-chloroethylisocyanate (II) in an inert medium at a temperature from 0-50 C, preferably in the presence of an alkaline agent. Suitable inert media for the reaction are dimethylformamide, dimethylsulfoxide, phosphoric acid, hexamethyltriamide or tetramethylurea. Alkaline agents, preferably tertiary organic amines, accelerate the reaction and make the yield of the desired product higher.

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