【药物名称】Flavalfate, Dosmalfate, F-3616M, F-3616, Diotul
化学结构式(Chemical Structure):
参考文献No.21654
标题:Sulfated diosmin deriv.
作者:Orjales-Venero, A.; Mosquera-Pestana, R. (FAES)
来源:EP 0558435; ES 2041216; JP 1994008677; US 5296469
合成路线图解说明:

Dosmalfate is obtained in a multistep synthesis: The treatment of anhydrous 5-ethyl-2-methylpyridine (I) with chlorosulfonic acid (II) affords 5-ethyl-2-methylpyridine sulfur trioxide complex (III). Heating 1 mol of diosmin (IV) with 7 mol of (III) gives diosmin heptakis(hydrogensulfate) 5-ethyl-2-methylpyridinium salt (V), which by treatment with aqueous sodium hydroxide yields the diosmin heptakis(hydrogensulfate) sodium salt. Finally, the reaction of the sodium salt in an aqueous medium with an aqueous aluminum hydroxychloride solution yields the diosmin heptakis(hydrogensulfate) aluminum complex.

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