【药物名称】PST-2107
化学结构式(Chemical Structure):
参考文献No.22549
标题:Cyclopentanperhydrophenanthren-17beta-(3-furyl)-3-derivs. and pharmaceutical compsns. comprising same for the treatment of cardiovascular disorders
作者:Quadri, L.; Bernardi, L.; Ferrari, P.; Gobbini, M.; Melloni, P.; Valentino, L. (Sigma-Tau Industrie Farmaceutiche Riunite SpA)
来源:EP 0576915; JP 1994065284; US 5432169
合成路线图解说明:

Reaction of furylandrostanediol (I) (J Chem Soc (C) 1966, 377) with bromoacetaldehyde diethylacetal (II) in the presence of NaH in refluxing tetahydrofuran provided ether (III). Subsequent acid hydrolysis of ethyl acetal of (III) gave aldehyde (IV), which was reduced to alcohol (V) with NaBH4. Coupling of (V) with phthalimide (VI) under Mitsunobu conditions produced the N-alkylated phthalimide (VII), and further hydrazinolysis yielded primary amine (VIII). The required guanidine function was finally introduced by treatment of (VIII) with 3,5-dimethyl-1-pyrazolylformamidinium nitrate (IX) in boiling EtOH.

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