【药物名称】CL-329167
化学结构式(Chemical Structure):
参考文献No.284970
标题:2,3,6-Substituted quinazolinones as angiotensin II receptor antagonists
作者:Levin, J.I.; Chen, P.S.; Porter, R.S.
来源:Drugs Fut 1995,20(1),55
合成路线图解说明:

The cyclization of 2-amino-5-iodobenzoic acid (I) with pentanoic anhydride (II) in basic medium gives 2-butyl-6-iodoquinazolin-4(3H)-one (III), which is condensed with CO and methanol by means of PdCl2(PPh3)2 and TEA yielding 2-butyl-4-oxo-3,4-dihydroquinazoline-6-carboxylic acid methyl ester (IV). The Grignard condensation of (IV) with methylmagnesium bromide affords the tertiary alcohol (V), which is finally condensed with the tetrazolylbiphenyl (VI) by means of LiOMe, methylated at the tertiary alcohol with methyl iodide and NaH, and deprotected with NaOH in methanol/THF.

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