【药物名称】RS-57067-000
化学结构式(Chemical Structure):
参考文献No.30052
标题:Pyrrole derivs.
作者:Barnett, J.W.; Dunn, J.P.; Kertesz, D.J.; Miller, A.B.; Morgans, D.J. Jr.; Ramesha, C.S.; Sigal, C.E.; Sjogren, E.B.; Smith, D.B.; Talamas, F.X. (F. Hoffmann-La Roche AG)
来源:CA 2163490; EP 0714895; JP 1996208639
合成路线图解说明:

The methylation of zomepirac (2-[5-(4-chlorobenzoyl)-1,4-dimethylpyrrol-2-yl]acetic acid sodium salt) (I) with methyl iodide in DMF gives the expected methyl ester (II), which is condensed with 3,6-dichloropyridazine (III) by means of NaH in DMF yielding 2-[5-(4-chlorobenzoyl)-1,4-dimethylpyrrol-2-yl]-2-(6-chloropyridazin-3-yl)acetic acid methyl ester (IV). The hydrolysis of (IV) with LiOH in methanol/water affords the corresonding lithium salt (V), which is decarboxylated in aqueous HCl yielding 1-(4-chlorophenyl)-1-[5-(6-chloropyridazin-3-yl)-1,3-dimethylpyrrol-2-yl]methanone (VI). Finally, this compound is treated with sodium acetate in refluxing acetic acid.

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