【药物名称】Y-27632
化学结构式(Chemical Structure):
参考文献No.12517
标题:Trans-4-amino(alkyl)-1-pyridylcarbamoylcyclohexane cpds. and pharmaceutical use thereof
作者:Muro, T.; Seki, T.; Abe, M.; Inui, J.; Sato, H. (Mitsubishi Pharma Corp.)
来源:EP 0370498; JP 1990509475; US 4997834; WO 9005723
合成路线图解说明:

Racemic trans-4-(1-benzyloxycarbonylaminoethyl)cyclohexanecarboxylic acid (I) was resolved using D-(+)-alpha-phenethylamine. The desired (R)-isomer (II) was activated as the corresponding acid chloride (III), which was further coupled with 4-aminopyridine (IV), yielding amide (V). The benzyloxycarbonyl protecting group of (V) was finally removed by treatment with HBr in HOAc.

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