【药物名称】NNC-26-9100
化学结构式(Chemical Structure):
参考文献No.478959
标题:Nonpeptide somatostatin agonists with sst4 selectivity: Synthesis and structure-activity relationships of thioureas
作者:Liu, S.; Tang, C.; Ho, B.; Ankersen, M.; Stidsen, C.E.; Crider, A.M.
来源:J Med Chem 1998,41(24),4693
合成路线图解说明:

Reaction of 2,5-dibromopyridine (I) with an excess of 1,3-diaminopropane (II) in refluxing pyridine provided N-1-(2-pyridyl)propanediamine (III). This compound was further alkylated at the 1N with 3,4-dichlorobenzyl chloride (IV) in DMSO using NaH as the base to afford (V). From this, isothiocyanate (VI) was prepared by reaction with CS2 and DCC in THF. Subsequent coupling with trityl-protected amine (VII) yielded the thiourea (VIII). Finally, the trityl protecting group was removed by refluxing in 1 N HCl.

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