【药物名称】PKI-75166, PKI-166, CGP-75166
化学结构式(Chemical Structure):
参考文献No.32339
标题:Pyrrolopyrimidines and processes for the preparation thereof
作者:Traxler, P.; Bold, G.; Brill, W.K.-D.; Frei, J. (Novartis AG)
来源:EP 0836605; JP 1999508570; US 6140332; WO 9702266
合成路线图解说明:

The cyclization of 4-methoxyphenacyl bromide (I) with 2-amidinoacetic acid ethyl ester (II) by means of sodium ethoxide in ethanol gives 2-amino-5-(4-methoxyphenyl)-1H-pyrrole-3-carboxylic acid ethyl ester (III), which is cyclized with formamide in DMF at 150 C to yield the pyrrolopyrimidine (IV). The reaction of the OH group of (IV) with POCl3 at 150 C affords the corresponding chloro derivative (V), which is condensed with 1(R)-phenylethylamine (VI) in refluxing butanol to provide the adduct (VII). Finally, this compound is demethylated by means of BBr3 in dichloromethane to furnish the target pyrrolopyrimidine.

Drug Information Express,Drug R&D,Chemical Database,Patent Search.
Copyright © 2006-2024 Drug Future. All rights reserved.Contact Us