【药物名称】SPD-473, BTS-74398
化学结构式(Chemical Structure):
参考文献No.25520
标题:1-Arylcycloalkyl sulphides, sulphoxides and sulphones for the treatment of depression, anxiety and Parkinson's disease
作者:Harris, P.J.; Heal, D.J. (The Boots Company plc)
来源:EP 0715620; JP 1996510222; US 5652271; WO 9426704
合成路线图解说明:

Addition of methylmagnesium iodide to nitrile (I), followed by hydrolytic treatment, provided ketone (II), which was brominated in CHCl3-MeOH to give bromomethyl ketone (III). Alkylation of thiourea (V) with 3-(dimethylamino)propyl chloride (IV) produced S-alkyl isothiourea (VI). After hydrolysis of (VI) with NaOEt, the intermediate thiol (VII) was condensed with bromoketone (III) to yield the required thioether, which was finally converted to the citrate salt.

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