【药物名称】
化学结构式(Chemical Structure):
参考文献No.482606
标题:Synthesis and evaluation of potent and selective c-GMP phosphodiesterase inhibitors
作者:Ho, G.D.; Silverman, L.; Bercovivi, A.; Puchalski, C.; Tulshian, D.; Xia, Y.; Czarniecki, M.; Green, M.; Cleven, R.; Zhang, H.; Fawzi, A.
来源:Bioorg Med Chem Lett 1999,9(1),7
合成路线图解说明:

The acylation of 6-amino-5-(benzylamino)-2-methylpyrimidine-2,4(1H,3H)-dione (I) with 5-methylhexanoic acid (II) by means of EDCI and DMAP gives the amide (III), which is cyclized by means of hot POCl3 affording the chloropurin-6-one (IV). The condensation of (IV) with the chiral aminoalcohol (V) by means of DIEA and NMP yields intermediate (VI), which is cyclized by means of SOCl2 in dichloromethane providing the imidazo-purine (VII). Finally, this compound is debenzylated with ammonium formate and Pd(OH)2.

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