【药物名称】D83-7676
化学结构式(Chemical Structure):
参考文献No.42058
标题:Pyrazole derivs. and salts thereof
作者:Naito, H.; Ohsuki, S.; Ejima, A.; Makino, C.; Ohki, H. (Daiichi Pharmaceutical Co., Ltd.)
来源:EP 1103551; JP 2000169475; WO 0005230
合成路线图解说明:

The deprotection of the benzyloxypyrimidine derivative (I) by treatment wit TFA and thioanisole gives the hydroxypyrimidine (II), which is treated with hot POCl3, yielding the corresponding chloro derivative (III). Finally, the target compound is obtained by condensation of (III) with 3-hydroxyazetidine (IV) in refluxing ethanol. The azetidine (IV) is obtained by deprotection of 1-benzhydryl-3-hydroxyazetidine (V) by hydrogenation with H2 over Pd/C in ethanol/water.

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