【药物名称】KNI-1039
化学结构式(Chemical Structure):
参考文献No.588587
标题:"Double-drugs" - a new class of prodrug form of an HIV protease inhibitor conjugated with a reverse transcriptase inhibitor by a spontaneously cleavable linker
作者:Matsumoto, H.; Hamawaki, T.; Ota, H.; Kimura, T.; Goto, T.; Sano, K.; Hayashi, Y.; Kiso, Y.
来源:Bioorg Med Chem Lett 2000,10(11),1227
合成路线图解说明:

Coupling of AZT (I) with Boc-Gly-OH (II) by means of dicyclohexyl carbodiimide (DCC) in the presence of dimethylaminopyridine (DMAP) in DMF followed by Boc removal by treatment with HCl/dioxane yields AZT ester (III). On the other hand, KNI-727 (IV) is condensed with glutaric anhydride (V) in THF-ether in the presence of dicyclohexylamine (DCHA) to yield the half ester of KNI-727 (VI), which is then condensed with derivative (III) by means of EDC.HCl in DMF in the presence of HOBt to furnish the target compound.

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