【药物名称】
化学结构式(Chemical Structure):
参考文献No.585704
标题:Synthesis and biological activities of an alpha-methyl and a beta-methyl carbapenem and the corresponding unsubstituted compound
作者:Pfaendler, H.R.; Weishaupt, R.; Meffert, H.
来源:Bioorg Med Chem Lett 2000,10(12),1389
合成路线图解说明:

Cyclization of azetidinone (I) by means of catalyst Rh2(OAc)4 in toluol provides carbapenam (II), which is treated with SiO2 in EtOAc to produce epimerization to the alpha-methyl compound (III). Methylation of (III) with diazomethane in dioxane affords carbapenem (IV), which is hydrogenolyzed over Pd/C in EtOAc and finally saponified with KHCO3 in H2O to furnish the desired compound.

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