【药物名称】
化学结构式(Chemical Structure):
参考文献No.36167
标题:Imidazoles with serotonin receptor binding activity
作者:Glennon, R.A.; Law, H. (NPS Allelix Corp.; Virginia Commonwealth University)
来源:US 5969137; WO 9812183
合成路线图解说明:

Alkylation of sodium cyanide with 4-tert-butyl-2,6-dimethylbenzyl chloride (I) afforded nitrile (II). Imidate (III) was then prepared by Pinner reaction of nitrile (II) with ethanolic HCl. Cyclization of (III) with 1,3-diaminopropane (IV) in ethanol furnished the desired cyclic amidine. In an alternative procedure, the target amidine was directly obtained by melting at 200 C nitrile (II) with the mono-tosylate salt of 1,3-diaminopropane.

参考文献No.616119
标题:Imidazoline-modified benzylimidazolines as h5-HT1D/1B serotonergic ligands
作者:Prisinzano, T.; Law, H.; Dukat, M.; Slassi, A.; MacLean, N.; Demchyshyn, L.; Glennon, R.A.
来源:Bioorg Med Chem 2001,9(3),613
合成路线图解说明:

Alkylation of sodium cyanide with 4-tert-butyl-2,6-dimethylbenzyl chloride (I) afforded nitrile (II). Imidate (III) was then prepared by Pinner reaction of nitrile (II) with ethanolic HCl. Cyclization of (III) with 1,3-diaminopropane (IV) in ethanol furnished the desired cyclic amidine. In an alternative procedure, the target amidine was directly obtained by melting at 200 C nitrile (II) with the mono-tosylate salt of 1,3-diaminopropane.

Drug Information Express,Drug R&D,Chemical Database,Patent Search.
Copyright © 2006-2024 Drug Future. All rights reserved.Contact Us