【药物名称】
化学结构式(Chemical Structure):
参考文献No.48809
标题:10-Substd. 18-dihydroxy-9(10H)anthracenone pharmaceuticals
作者:Reindl, H.; Muller, K.; Weigrebe, W. (Teva Pharmaceutical Industries Ltd.)
来源:US 5952390
合成路线图解说明:

Acylation of anthralin (I) either with phenylacetic acid (II) by means of EDC and pyridine in THF or with phenylacetyl chloride (III) by means of pyridine in THF affords compound (IV), which is finally converted into the desired hydroxamate by reaction with N-methyl-N-hydroxylamine and EDC in DMF.

合成路线图解说明:

Acid chloride (II) was prepared by treatment of 4-phenylvaleric acid (I) with thionyl chloride. Condensation of acid chloride (II) with dithranol (III) in the presence of pyridine provided the title compound.

参考文献No.617972
标题:10-Phenylbutyryl-substituted anthracenones as inhibitors of keratinocyte growth and LTB4 biosynthesis
作者:M黮ler, K.; Breu, K.; Reindl, H.
来源:Eur J Med Chem 2001,36(2),179
合成路线图解说明:

Acid chloride (II) was prepared by treatment of 4-phenylvaleric acid (I) with thionyl chloride. Condensation of acid chloride (II) with dithranol (III) in the presence of pyridine provided the title compound.

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