【药物名称】
化学结构式(Chemical Structure):
参考文献No.627769
标题:Reduced amide bond peptidomimetics. (4S)-N-(4-Amino-5-(aminoalkyl]aminopentyl)-N'-nitroguanidines, potent and highly selective inhibitors of neuronal nitric oxide synthase
作者:Hah, J.-M.; Roman, L.J.; Martasek, P.; Silverman, R.B.
来源:J Med Chem 2001,44(16),2667
合成路线图解说明:

Boc-Nitroarginine (I) was activated as the mixed anhydride (II), which was further converted to the Weinreb amide (III) upon treatment with N,O-dimethylhydroxylamine. Reduction of (III) with LiAlH4 furnished N-Boc-nitroargininal (IV). This was reductively condensed with the mono-Boc-protected ethylenediamine (V) in the presence of sodium triacetoxyborohydride, yielding amine (VI). The Boc protecting groups of (VI) were finally removed by treatment with trifluoroacetic acid to provide the title compound.

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