【药物名称】
化学结构式(Chemical Structure):
参考文献No.656989
标题:Novel use of a guanosine prodrug approach to convert 2',3'-didehydro-2',3'-dideoxyguanosine into a viable antiviral agent
作者:Ray, A.S.; Yang, Z.; Chu, C.K.; Anderson, K.S.
来源:Antimicrob Agents Chemother 2002,46(3),887
合成路线图解说明:

Treatment of 2-amino-6-chloro-9-beta-D-ribofuranosylpurine (I) with acetoxyisobutyryl bromide (II) led to a mixture of acetoxy bromo derivatives (III) and (IV) which, upon reductive treatment with activated zinc, furnished the 2',3'-dehydro compound (V). Deprotection of (V) with K2CO3 in aqueous methanol provided the free nucleoside (VI). Finally, nucleophilic displacement of the chlorine of (VI) with cyclopropylamine (VII) afforded the target compound.

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