【药物名称】CC-3
化学结构式(Chemical Structure):
参考文献No.667041
标题:Novel heterocyclic-fused pyridazinones as potent and selective phosphodiesterase IV inhibitors
作者:Dal Piaz, V.; Giovannoni, M.P.; Castellana, C.; Palacios, J.M.; Beleta, J.; Domenech, T.; Segarra, V.
来源:J Med Chem 1997,40(10),1417
合成路线图解说明:

Cyclization of ethyl 4-benzoyl-5-methylisoxazole-3-carboxylate (I) with hydrazine hydrate affords the isoxazolopyridazinone (II). Regioselective alkylation of (II) with ethyl bromide gives the 6-ethyl derivative (III). This is then subjected to oxidative isoxazole ring cleavage with cerium ammonium nitrate to furnish the nitro ketone (IV). Finally, cyclization of (IV) with ethanolic hydrazine leads to the target pyrazolopyridazinone.

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