【药物名称】
化学结构式(Chemical Structure):
参考文献No.711815
标题:Core-modified sordaricin derivatives: Synthesis and antifungal activity
作者:Regueiro-Ren, A.; Carroll, T.M.; Chen, Y.; Matson, J.A.; Huang, S.; Mazzucco, C.E.; Stickle, T.M.; Vyas, D.M.; Balasubramanian, B.N.
来源:Bioorg Med Chem Lett 2002,12(23),3403
合成路线图解说明:

Prolonged exposure of sordaricin (I) to Nocardia species SC11274 affords 7 hydroxysordaricin (II). Acid-promoted dehydration of the tertiary alcohol (II) using 6 N HCl in acetone generates 7,8-deshydrosordaricin (III), which is further protected as the benzyl ester (IV) upon treatment with O-benzyl diisopropyl isourea. Then, alkylation of the primary hydroxyl group of (IV) with 1 iodohexane (V) gives rise to the corresponding hexyl ether (VI). Finally, the benzyl ester group in (VI) is cleaved by hydrogenolysis to furnish the title compound.

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