Title: Jasmolins
Literature References: Active insecticidal constituents of pyrethrum flowers. Isoln and structure: Godin et al., J. Econ. Entomol. 58, 548 (1965); Godin et al., J. Chem. Soc. C 1966, 322. Stereochemistry: Begley et al., Chem. Commun. 1972, 1276. Review of toxicology and human exposure: Toxicological Profile for Pyrethrins and Pyrethroids (PB2004-100004, 2003) 332 pp.
Derivative Type: Jasmolin I
CAS Registry Number: 4466-14-2
CAS Name: (1R,3R)-2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid (1S)-2-methyl-4-oxo-3-(2Z)-2-pentenyl-2-cyclopenten-1-yl ester
Additional Names: 4¢,5¢-dihydropyrethrin I
Molecular Formula: C21H30O3
Molecular Weight: 330.46
Percent Composition: C 76.33%, H 9.15%, O 14.52%
Properties: Liquid. uv max (Spectrosol hexane): 219 nm (e 21500).
Absorption maximum: uv max (Spectrosol hexane): 219 nm (e 21500)
Derivative Type: Jasmolin II
CAS Registry Number: 1172-63-0
CAS Name: (1R,3R)-3-[(1E)-3-Methoxy-2-methyl-3-oxo-1-propenyl]-2,2-dimethylcyclopropanecarboxylic acid (1S)-2-methyl-4-oxo-3-(2Z)-2-pentenyl-2-cyclopenten-1-yl ester
Additional Names: 4¢,5¢-dihydropyrethrin II
Molecular Formula: C22H30O5
Molecular Weight: 374.47
Percent Composition: C 70.56%, H 8.07%, O 21.36%
Properties: Liquid. uv max (Spectrosol hexane): 229 nm (e 22900).
Absorption maximum: uv max (Spectrosol hexane): 229 nm (e 22900)
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